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Aerosol monitoring program at Izaña Atmospheric Observatory

Objective

Measurements

Research

Visitors for aerosol studies

Publications

Pictures

 

Objective

The objective is to perform a continuous monitoring of the aerosol properties related to climate forcing and air quality on multi-decadal time scales in the subtropical North Atlantic free troposphere. For this purpose, particle size, chemical composition and optical properties at monitored in a continuous basis. This project is performed within the framework of the Global Atmospheric Watch (GAW) program of the World Meteorological Organization.

Measurements

PARTILAB

The instrumentation used for performing the in-situ aerosol measurements are placed in a building so-called PARTILAB (particles laboratory):




View of the PARTILAB building.

INLETS

Currently, three inlets are use in the PARTILAB, two inlets for collecting TSP, PM10 and PM2.5 samples and one main inlet where instruments for on line measurements are connected:

Inlets of the PARTILAB.

RACKS

Two of our particle samplers are installed within independent racks:

View of two of the sampler in the PARTILAB.

 

 

 


Another rack used for placing the instruments for on line measurements. This is placed below the main inlet. The laminar airflow in this inlet is isokinetically split for providing the aerosol sample to each instrument:
View of the main inlet of the PARTILAB.

View of the instrumentation used for on line aerosol measurements.
INSTRUMENTS
Parameter
Instrument picture

Number concentrations of particles coarser 3 nm is measured with a TSI™ Ultrafine Condensation Particle Counter model 3025A.


Size distribution of particles 9 – 437 nm diameter is measured with a TSI™ Scanning Mobility Particle Sizer (SMPS). A CPC model 3010 and a DMA model 3081 are used.

Size distribution of particles 0.5 – 20 µm diameter, measured with a TSI™ Aerodynamic Particle Sizer (APS) model 3321.

Mass concentrations and chemical composition of Total Suspended (TSP), less than 10 microns (PM10) and less than 2.5 microns (PM2.5) particles is determined by sampling on quartz micro fiber filter.

Mass concentration is determined by gravimetry in our laboratory.

Chemical composition allows determining the concentrations of mineral dust, sea salt, sulphate, nitrate, ammonium, organic carbon, elemental carbon, trace elements.


Absorption coefficient at 1 wavelength (630 nm light), due to particles smaller than 10 microns, is measured with a Thermo™ MultiAngle Absorption Photometer (MAAP). A PM10 impactor is placed in the inlet.

Total-scattering (7-170 degrees) and back-scattering (90-170 degrees) due to particles smaller than 10 microns, is measured at 3 wavelengths: blue (450 nm), green (550 nm) and red (700 nm). A TSI™ Integrating Nephelometer model 3563 is used. A PM10 impactor is placed in the inlet.

More details on the measurements are provided at GAWSIS

Research

Aerosol studies in Izaña Observatory are focused on Saharan dust transport, dust optical properties, dust climatology, new particle formation and free troposphere aerosols.

Saharan dust transport mainly occurs in summer, when the Saharan Air Layer is westward transported across the Atlantic by passing over the Canary Islands. TSP, PM10 and PM2.5 concentrations are Izaña are usually extremely low due to the clean air conditions in the free troposphere conditions (e.g., the PM10 and PM2.5 median for the 2004-2008 period are equal to 3.5 and 2.2 µg/m3, respectively). Increases in the aerosol mass concentrations are only recorded during Saharan dust transport episodes. High TSP, PM10 and PM2.5 concentrations are only recorded in summer due to dust transport.

 

Monthly average values of PM10 and PM2.5 concentrations.

Global Aerosol Optical Depth. Red circle highlights the location of Izaña in the Northern edge of the Saharan Air Layer.

Optical Properties. Atmospheric particles scatter and may absorb light. This affects the radiation and energy distribution in the atmosphere. In the example shown in the Figure below two different situations are shown. In the mid June 2008 example, the highest scattering occurs for blue light due to the very small size (mostly Aitken particles) and concentrations (<5 µg/m3) of the free troposphere aerosols. Since ending June 2008, the presence of reddish Saharan dust particles resulted in high scattering of light.
Hourly values of the total scattering coefficient at three wavelengths (700, 550 and 450 nm) and of the PM10 particles concentration.
New particle formation is observed almost every day in the upward oropharic flows that develops during daylight around Tenerife Island. These upward flows result in the transport of water vapor and gaseous precursors from the boundary layer (at low altitudes, where these are emitted) to the low free troposphere. These particles have an initial size of a few nanometers, and they may growth up to reach a size within the range 50 to 100 nm. These particles are formed above the layer of marine stratocumulus typical of the subtropical atmospheres.
Daily evolution for every month of, relative humidity (RH), water vapor (H2O), temperature (ºC), and the concentrations of particles with a diameters within the range 3-10nm (N3-10), higher than 10nm (N10) and higher than 3 nm (N3).

Picture of the northern side of Tenerife (view from Izaña Observatory) showing how the terrain of the island emerges above the marine stratocumulus cloud layer and enters in the low free troposphere.

5-minute values of the dN/dlogD size distribution during a new particle formation event.

Visitors for aerosol studies (since 2003)

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Name
Institution
Period
Scientist of the MINATROC project

August 2003
Dr. S. Castillo
Institute of Earth Sciences “Jaume Almera”, CSIC
August 2003
Prof. J. M. Prospero
RSMAS-University of Miami
August 2005
Dr. K. Kandler
Darmstadt University of Technology
July 2005
Dr. M. Gil and Mr. J.F. López
INTA
July 2005
Dr. M. Gil and Mr. J. Andrey
INTA
July 2006
Dr. T. Tuch and A. Nowak
World Calibration Centre for Aerosol Physics
November 2006
Isabel García Alvarez
University of La Laguna
January – June 2009
S. Scheidt
University of Pittsburgh
July 2009
Fluvio Amato
IDAEA-CSIC
July 2010
Yvonne Boose , Larissa Lacher, Berko Sierau
Institute for Atmospheric and Climate Science of Zürich (ETH)
July-August 2013
Susan Schmidt
Max Planck Institute for Chemistry (MPI-C)
July-August 2013
Yvonne Boose , Fabian Mahrt, Berko Sierau
Institute for Atmospheric and Climate Science of Zürich (ETH)
July-August 2014

Publications based on aerosol observations at Izaña

 

Querol, X., A. Alastuey, M. Viana, T. Moreno, C. Reche, M.C. Minguillón, A. Ripoll, M. Pandolfi, F. Amato, A. Karanasiou, N. Pérez, J. Pey, M. Cusack, R. Vázquez, F. Plana, M. Dall’Osto, J. de la Rosa, A. Sánchez de la Campa, R. Fernández-Camacho, S. Rodríguez, C. Pío, L. Alados-Arboledas, G. Titos, B. Artíñano, P. Salvador, S. García Dos Santos, R. Fernández Patier. Variability of carbonaceous aerosols in remote, rural, urban and industrial environments in Spain: Implications for air quality policy. Atmospheric Chemistry and Physics 13, 6185-6206, 2013. DOI: doi:10.5194/acp-13-6185-2013

García, M. I., S. Rodríguez, Y. González, R. D. García. Climatology of new particle formation events in the subtropical North Atlantic free troposphere at Izaña GAW observatory. Atmos. Chem. Phys. Discuss., 13, 24127–24169, 2013

Rodríguez, S. A. Alastuey, X. Querol. A review of methods for long term in-situ characterization of aerosol dust. Aeolian Research, 6, 55-74, 2012. DOI: http://dx.doi.org/10.1016/j.aeolia.2012.07.004

Schulz, M., J. M. Prospero, A. R. Baker, F. Dentener, L., Ickes, P.S. Liss, N. M. Mahowald, S. Nickovic, C. Pérez García-Pando, S. Rodríguez, M. Sarin, I. Tegen, R. A. Duce. Atmospheric Transport and Deposition of Mineral Dust to the Ocean: Implications for Research Needs. Environmental Sciences and Technology, 46, 10390−10404, ,2012. DOI: dx.doi.org/10.1021/es300073u

Andrews, E., J.A. Ogren, P. Bonasoni, A. Marinoni, E. Cuevas, S. Rodríguez, J.Y. Sun, D.A. Jaffe, E.V. Fischer, U. Baltensperger, E. Weingartner, M. Collaud Coen, S. Sharma, A.M. Macdonald, W.R. Leaitch, N.-H. Lin, P. Laj, T. Arsov, I. Kalapov, A. Jefferson, P. Sheridan. Climatology of aerosol radiative properties in the free troposphere. Atmospheric Research, 102(4), 365-393, 2011. DOI: 10.1016/j.atmosres.2011.08.017.

Rodríguez, S., A. Alastuey, S. Alonso-Pérez, X. Querol, E. Cuevas, J. Abreu-Afonso, M. Viana, M. Pandolfi, and J. de la Rosa. Transport of desert dust mixed with North African industrial pollutants in the subtropical Saharan Air Layer. Atmospheric Chemistry and Physics, 11, 6663 – 6685.

Rodríguez, S., González, Y., Cuevas, E., Ramos, R., Romero, P.M., Abreu-Afonso, J., Redondas, A., Atmospheric nanoparticle observations in the low free troposphere during upward orographic flows at Izaña Mountain Observatory. Atmospheric Chemistry and Physics Discussions, 9, 10913–10956, 2009. Still in open discussion period !!! (download pdf)

Kandler, K., N. Benker, E. Cuevas, M. Ebert, P. Knippertz, S. Rodríguez, L. Schütz, S. Weinbruch, Chemical composition and complex refractive index of Saharan Mineral Dust at Izaña, Tenerife (Spain) derived by electron microscopy. Atmospheric Environment, 41, 8058–8074, 2007. DOI: 10.1016/j.atmosenv.2007.06.047

Alastuey, A., Querol, X., Castillo, S., Escudero, M., Avila, A., Cuevas, E., Torres, C., P.M. Romero, Exposito, F., García, O., Díaz, J.P., Van Dingenen, R., Putaud, J.P.: Characterisation of TSP and PM2.5 at Izaña and Santa Cruz de Tenerife (Canary Islands, Spain) during a Saharan Dust Episode (July 2002). Atmospheric Environment 39, 4715–4728, 2005.

Maring, H., Savoie, D. L., Izaguirre, M. A., McCormick, C., Arimoto, R., Prospero, J. M., Pilinis, C.: Aerosol physical and optical properties and their relationship to aerosol composition in the free troposphere at Izaña, Tenerife, Canary Islands, during July 1995, Journal of Geophysical Research, 105, 14677–14700, 2000.

Chiapello, I., Prospero, J.M., Herman, J.R., Hsu, N.C., Detection of mineral dust over the North Atlantic Ocean and Africa with Nimbus 7 TOMS. Journal of Geophysical Research, 104, 9277-9291, 1999.

Raes, F., Van Dingenen, R., Cuevas, E., Van Velthoven, F.J.V., Prospero, J.M.: Observations of aerosols in the free troposphere and marine boundary layer of the subtropical Northeast Atlantic: discussion of processes determining their size distribution. Journal of Geophysical Research, 102, 21315-21328, 1997.

Prospero, J.M., Schmitt, R., Cuevas, E., Savoie, D.L., Graustein, W.C., Turekian, K.K., Volz- Thomas, A., Díaz, A., Oltmans, S.J., Levy, H., 1995. Temporal variability of summer-time ozone and aerosols in the free troposphere over the eastern North Atlantic. Geophysical Research Letters 22 (21), 2925–2928.

Abel, N., Jaenicke, R., Junge, C., Kanter, H., Rodríguez-García-Prieto, P., Seiler, W.. Luftchemische Studien am Observatorium Izaña (Teneriffa). Met. Rdsch., 22, p. 158, 1969.